Synthesis and Characterization of Amphiphilic Iron-Sulfur Core Dendrimers

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Date

2005-07-31

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Abstract

Synthesis of water soluble carboxylate-terminated Fe4S4-core was carried out. Convergent method was chosen to build three generations of dendrons. Several synthetic schemes were explored. The syntheses were conducted with 4,4-bis(hydroxyphenyl)penthanol as a repeat unit and N,N-dimethyl thiocarbamate and methyl ester or methoxy-methyl as protecting groups. The conditions for deprotection and ligand exchange have been proposed. 1H, 13C and MALDI-MS were used to characterize synthesized molecules.

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Keywords

Dendrimer, Encapsulation, Structure-Property Relationships, Iron-Sulfur Cluster

Citation

Degree

MS

Discipline

Chemistry

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