Computer Simulation Studies of Self-Assembly of Dipolar and Quadrupolar Colloid Particles

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dc.contributor.advisor Carol K. Hall, Committee Chair en_US
dc.contributor.advisor Keith E. Gubbins, Committee Member en_US
dc.contributor.advisor Orlin D. Velev, Committee Co-Chair en_US
dc.contributor.advisor Donald W. Brenner, Committee Member en_US Goyal, Amit en_US 2010-04-02T18:40:09Z 2010-04-02T18:40:09Z 2009-03-24 en_US
dc.identifier.other etd-03192009-182332 en_US
dc.description.abstract Colloidal particles with directional interactions that self-assemble into pre-defined microstructures have the potential to serve as the foundation for a new generation of micro- and nano-structures of remarkable complexity and precision. Dipolar colloid particles tend to align end-to-end and self-assemble into variety of micro- and nano-structures ranging from co-crystals of novel symmetry, to open networks (gels) of cross-linked chains of particles. Quadrupolar colloid particles also tend to self-assemble in a wide variety of structural motifs including sheets, tubes and shells depending upon external conditions. We use molecular dynamics computer simulation to explore the self-assembly, structure, crystallization and/or gelation of systems of colloid particles with permanent dipole moments or quadrupole moments immersed in a high-dielectric solvent. Particle-particle interactions are modeled with discontinuous potentials in order to take advantage of discontinuous molecular dynamics (DMD), a fast simulation technique that is very computationally efficient. We first calculate the phase diagram of monodisperse system of dipolar colloid particles using DMD in the temperature-packing fraction plane. Several types of phases are found in our simulations: ordered phases including face centered cubic (FCC), hexagonal close packing (HCP) and body centered tetragonal (BCT) at high packing fractions, and fluid, string-fluid and gel phases at low packing fractions. The very low volume fraction gel phases and the well ordered crystal phases are promising for advanced materials applications. We then examine how the phase diagram changes upon varying the sizes of the two species as well as their dipole moments. The phase diagrams of an equimolar binary mixture of dipolar colloid particles with different diameter ratios and different dipole moment ratios are calculated in the temperature-volume fraction plane. These systems exhibit six distinct phases: isotropic fluid, string-fluid, gel, FCC, HCP, BCT, and ten coexisting phases: Fluida + String-fluidb, Fluida + Gelb, String- Fluida + Gelb, Gela + BCTb, FCCa + FCCb, FCCa + HCPb, FCCa + FCCb+ Fluid, HCPa + HCPb, BCTa + BCTb, BCTa + BCTb + large voids depending upon size ratio and dipole moment ratio. An interesting aspect of these phase diagrams is the appearance of co-crystals containing large and small dipolar colloid particles at size ratio equal to 0.414. Even more interesting is the appearance of two unique bicontinuous gel structures - the first gel consists of two independent, but interpenetrating, networks of cross-linked chains formed by particles with high dipole moment and chains formed by particles with low dipole moment. The second type of gel consists of network of cross-linked chains formed by particles with high dipole moment, while particles with low dipole moment form a sheath around the chains. Such bicontinuous gels may have unusual rheological and transport properties such as multiple yield stresses and multiple percolation temperatures and could form the basis of new classes of soft-solid materials with unique properties and multiple applications. We also explore the structure formation of systems of colloid particles with permanent quadrupole moment. We introduce simple quadrupole-quadrupole discontinuous potential model that give rise to the self-organization of random surface (membrane), tubular (nanotubes) structures. We find that the discrete rotational symmetry of the quadrupolar particles give rise to extended two-dimensional random sheet or surface structures that preserve the local symmetry within the organized structure. A new type of anisotropic colloid particle is introduced having displaced quadrupole moment of a unique symmetry that leads to the formation of tubular structure. The precise diameter and length of the tubes can be controlled by tuning the interactions and temperature. Our simulations predict the optimal conditions for making the tubes of precise diameter and length using quadrupolar colloidal particles which may be the route to the formation of high quality nanotubes. en_US
dc.rights I hereby certify that, if appropriate, I have obtained and attached hereto a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dis sertation, or project report, allowing distribution as specified below. I certify that the version I submitted is the same as that approved by my advisory committee. I hereby grant to NC State University or its agents the non-exclusive license to archive and make accessible, under the conditions specified below, my thesis, dissertation, or project report in whole or in part in all forms of media, now or hereafter known. I retain all other ownership rights to the copyright of the thesis, dissertation or project report. I also retain the right to use in future works (such as articles or books) all or part of this thesis, dissertation, or project report. en_US
dc.subject quadrupolar en_US
dc.subject dipolar en_US
dc.subject self-assembly en_US
dc.title Computer Simulation Studies of Self-Assembly of Dipolar and Quadrupolar Colloid Particles en_US PhD en_US dissertation en_US Chemical Engineering en_US

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